Drinking Water

The essential elements selenium (Se) and iodine (I) are often present in low levels in terrestrial diets, leading to potential deficiencies. Marine I and Se emissions and subsequent atmospheric wet deposition has been suggested to be an important source of I and Se to soils and terrestrial food chains. However, the contribution of recycled moisture of continental origin to I and Se to precipitation has never been analyzed. Here we report concentrations and speciation of I and Se, as well as of bromine (Br), sulfur (S), and DOC-δ¹³C signatures for weekly collected precipitation samples (in the period of April 2015 to September 2016) at two high altitude sites, i.e., Jungfraujoch (JFJ; Switzerland) and Pic du Midi (PDM; France). Analysis of precipitation chemistry and moisture sources indicate combined marine and continental sources of precipitation and Se, I, Br, and S at both sites. At JFJ, concentrations of I and Se were highest when continental moisture sources were dominant, indicating important terrestrial sources for these elements. Furthermore, correlations between investigated elements and DOC-δ¹³C, particularly when continental moisture source contributions were high, indicate a link between these elements and the source of dissolved organic matter, especially for I (JFJ and PDM) and Se (JFJ).

Photodegradation processes play an important role in releasing elements tied up in biologically refractory forms in the environment, and are increasingly recognized as important contributors to biogeochemical cycles. While complete photooxidation of dissolved organic carbon (to CO₂), and dissolved organic phosphorous (to PO₄^3-) has been documented, the analogous photoproduction of sulfate from dissolved organic sulfur (DOS) has not yet been reported. Recent high-resolution mass spectrometry studies showed a selective loss of organic sulfur during photodegradation of dissolved organic matter, which was hypothesized to result in the production of sulfate. Here, we provide evidence of ubiquitous production of sulfate, methanesulfonic acid (MSA) and methanesulfinic acid (MSIA) during photodegradation of DOM samples from a wide range of natural terrestrial environments. We show that photochemical production of sulfate is generally more efficient than the production of MSA and MSIA, as well as volatile S-containing compounds (i.e., CS₂ and COS). We also identify possible molecular precursors for sulfate and MSA, and we demonstrate that a wide range of relevant classes of DOS compounds (in terms of S oxidation state and molecular structure) can liberate sulfate upon photosensitized degradation. This work suggests that photochemistry may play a more significant role in the aquatic and atmospheric fate of DOS than currently believed.

This study focused on the effects of ozonation on the photochemical and photophysical properties of dissolved organic matter (DOM). Upon ozonation, a decrease in DOM absorbance was observed in parallel with an increase in singlet oxygen (¹O₂) and fluorescence quantum yields (Φ_1O2 and Φ_F). The increase in Φ_1O2 was attributed to the formation of quinone-like moieties during ozonation of the phenolic moieties of DOM, while the increase in Φ_F can be explained by a significant decrease in the internal conversion rate of the first excited singlet state of the DOM (¹DOM*). It is a consequence of an increase in the average energy of the first electronic transition (S₁ → S₀) that was assessed using the wavelength of maximum fluorescence emission (λ_F,max). Furthermore, ozonation did not affect the ratio of the apparent steady-state concentrations of excited triplet DOM (³DOM*) and ¹O₂, indicating that ozonation does not affect the efficiency of ¹O₂ production from ³DOM*. The consequences of these changes for the phototransformation rates of micropollutants in surface waters were examined using photochemical model calculations. The decrease in DOM absorbance caused by ozonation leads to an enhancement of direct photolysis rates due to the increased transparency of the water. Rates of indirect photooxidation induced by ¹O₂ and ³DOM* slightly decrease after ozonation.

Environments that receive fecal pollution are reservoirs of antibiotic resistance. Recent metagenomic observations suggest that the fecal pollution indicator crAssphage correlates with the occurrence of antibiotic resistance genes (ARGs) in the environment. Expanding the utility of crAssphage to represent the environmental occurrence of ARGs would potentially facilitate ARG management in environments contaminated with fecal pollution. In this study, we analyzed a suite of molecular indicators for ARGs and crAssphage over a 30 day sampling period in an urban stream that receives combined sewer overflows. The sampled stream showed high levels of ARGs and crAssphage with statistically significantly elevated levels during wet weather events. The observed correlation between crAssphage and ARG molecular detection was high when all were measured using digital droplet polymerase chain reaction (PCR). Quantitative PCR and digital droplet PCR quantifications of crAssphage showed only moderate agreement, emphasizing the importance of detection technology when making quantitative comparisons. Overall, this study demonstrates the potential of a crAssphage fecal indicator to correlate with ARG occurrence when employing a "toolbox" approach to fecal pollution management.

Urban water systems are being redefined for a digital age, promising substantial advantages for service users and providers, and for society as a whole. However, beside the much-discussed benefits of smart urban water systems in future smart cities, the transition will also bring unique challenges, particularly with respect to privacy and cybersecurity. A preemptive delineation of these risks and providing appropriate recommendations will help to guide digital transformations of urban water towards sustainable solutions. Faced with emerging risks of digitalization, urban water management needs to look beyond technology while recognizing the central and multifaceted role of research.
In smart city initiatives, urban water systems remain largely out of the digitalization spotlight compared to other types of infrastructure. Oftentimes, the management and planning of urban water systems still follow traditional, steel and concrete-based approaches that treat used water as waste and not as a resource [1]. The need for innovation, however, is significant: the infrastructure, operation, and maintenance cost of urban water systems around the world already ranges in the hundred billion dollars annually and water-related stresses are expected to continue rising. Digitalization could not only increase the flexibility and effectiveness of existing urban water systems, but could also allow for the provisions of new services to society. The envisioned transformation, as outlined for example in the literature [2–4], entails novel data collection and transmission techniques, analytical methods, models, and automation. For example, smart water meter data can be combined with noise loggers to detect and roughly locate leaks in water mains. Together with automated control infrastructure, pressure can be regulated to reduce water losses [4]. By this and numerous other smart solutions, not only water distribution but also sewers and wastewater treatment will be transformed. In particular, digitalization facilitates large-scale implementation of disruptive technologies like decentralized wastewater treatment [5] and direct potable reuse, which will help cities to cope with climate change and urbanization.
However, we argue that as the benefits of smart urban water systems are increasingly explored and showcased in literature, it is time to also give attention to potential risks that might emerge. Recurring data breaches and the growing use of cyber-attacks for geopolitical ends are a reminder that the digitalization of society indeed carries risks. Given the critical role of water services in society and within the water-energy-food nexus, these risks must be identified and managed pro-actively. In the following, we raise awareness and suggest ways forward in approaching the unique privacy and security issues that accompany the digitalization of urban water systems. Finally, we highlight the central role of researchers in assessing and mitigating the potential risks of the smart urban water solutions they propose.