Département Ressources aquatiques et eau potable

Combustion of sewage sludge has become a viable route for sewage sludge management especially as the agricultural use of sewage sludge has become increasingly difficult due to more stringent requirements regarding the quality of sewage sludge. Combustion of digested sewage sludge in dedicated monocombustion facilities is advantageous, as it substantially reduces the volume of the sludge and still allows for a recovery of phosphorus from the sewage sludge ash at a later stage. Despite increasing amounts of sewage sludge being combusted, knowledge on the respective combustion kinetics is still fragmentary. The goal of this study was, therefore, to identify the major combustion reactions of sewage sludge, assess their Arrhenius parameters (activation energy and pre-exponential factor), and assign suitable reference compounds to the individual reactions. For that purpose, experiments were conducted using a thermogravimetric analyzer (TGA). With matrix inversion, we identified 10 individual reactions. Despite the apparent kinetic compensation most likely caused by insufficient precision of the TGA temperature setting, we were able to relate the major reactions of sewage sludge combustion to the combustion of individual reference compounds. In addition to cellulose and lignin, which dominated the weight loss with 35% and 20%, respectively, hemicellulose, xylan, alginate, and calcite were identified. The dominant fraction of cellulose is consistent with recent studies identifying cellulose mainly originating from toilet paper as a major organic constituent in wastewater. As the identified model compounds explain more than 80% of the total weight loss observed, our approach allows a rough speciation of the combustibles of sewage sludge based on TGA experiments.

Im Wassergewinnungsgebiet Hardwald werden rund 15 Mio. m³/a Trinkwasser produziert. Es finden sich jedoch Spuren von chlorierten organischen Verbindungen im Grundwasser. Als Fallstudie werden hier die Ergebnisse von Feld- und Laborarbeiten zur Bestimmung der räumlichen Verteilung der chlorierten organischen Verbindungen, der stabilen Wasserisotope (δ¹⁸O und δ²D), der Hauptkationen- und -anionen und ausgewählter Spurenstoffe, welche über ein Rheininfiltrat eingetragen werden, vorgestellt. Als Ergebnis der Untersuchungen zeigte sich, dass die künstliche Rheinwasserinfiltration ganz entscheidend zur Trinkwassersicherheit beiträgt und das entnommene Grundwasser vorwiegend der chemischen Signatur des infiltrierten Rheinwassers entspricht. Jedoch zeigt sich auch, dass durch die über die Fläche ungleichmäßig verteilte Infiltration vor allem eine Beimischung von Muschelkalkwasser in süd-westlichen Bereichen des Untersuchungsgebiets wahrscheinlich ist. Diese Interpretation wird durch die Verteilung der chlorierten organischen Verbindungen, Hauptkationen- und -anionen, stabilen Wasserisotopen und Spurenstoffen gestützt. Trotz der hier vorhandenen komplexen Randbedingungen wird durch das Zusammenspiel von künstlicher Infiltration und Entnahme eine sichere Trinkwasserversorgung ermöglicht.

The semi-arid Sahel regions of West Africa rely heavily on groundwater from shallow to moderately deep (<100 m b.g.l.) crystalline bedrock aquifers for drinking water production. Groundwater quality may be affected by high geogenic arsenic (As) concentrations (>10 μg/L) stemming from the oxidation of sulphide minerals (pyrite, arsenopyrite) in mineralised zones. These aquifers are still little investigated, especially concerning groundwater residence times and the influence of the annual monsoon season on groundwater chemistry. To gain insights on the temporal aspects of As contamination, we have used isotope tracers (noble gases, ³H, stable water isotopes (²H, ¹⁸O)) and performed hydrochemical analyses on groundwater abstracted from tube wells and dug wells in a small study area in southwestern Burkina Faso. Results revealed a great variability in groundwater properties (e.g. redox conditions, As concentrations, water level, residence time) over spatial scales of only a few hundred metres, characteristic of the highly heterogeneous fractured underground. Elevated As levels are found in oxic groundwater of circum-neutral pH and show little relation with any of the measured parameters. Arsenic concentrations are relatively stable over the course of the year, with little effect seen by the monsoon. Groundwater residence time does not seem to have an influence on As concentrations, as elevated As can be found both in groundwater with short (<50 a) and long (>10³ a) residence times as indicated by ³He/⁴He ratios spanning three orders of magnitude. These results support the hypothesis that the proximity to mineralised zones is the most crucial factor controlling As concentrations in the observed redox/pH conditions. The existence of very old water portions with residence times >10³ years already at depths of <50 m b.g.l. is a new finding for the shallow fractured bedrock aquifers of Burkina Faso, suggesting that overexploitation of these relatively low-yielding aquifers may be an issue in the future.